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What are the minerals processing industries ?
Date posted:
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Post Author
espadmin
1. Introduction
The minerals processing industries constitute the largest annual tonnage manufacturers on a worldwide basis, of which some 1500millon tonnes per annum of minerals are processed at temperatures in excess of 1000oC. The general term for high temperature (<800oC) processing of material is [GLOSS]calcination[/GLOSS], and the term bears no relationship to the particular chemical or physical changes that are effected in the kiln. Over 80% of this production is dedicated to the manufacture of cements which consumes >5000PJ.p.a. of primary energy, mainly in the form of [GLOSS]coal[/GLOSS].
2. Minerals processing
Typical industries that fall within the minerals processing sector include:
· Cement
· Lime
· Alumina
· Magnesite
· Chromium and titanium dioxide
Other related operations, such as:
· dead burnt petroleum coke production and
· metal ore fines roasting
may also be considered within this sector as they use similar technologies.
Whilst the individual process thermodynamics and chemistry requirements are different for the type of minerals being processed there are some basic similarities in the process cycles and equipment used. Counter-current flow of process material and process gases tends to be a common design feature, whereby the feed of raw material is preheated/pre-processed by the flue gases from the primary furnace(s). The primary furnace(s) calcine the product, heat being supplied by direct contact with a diffusion flame. The combustion air to the furnace is generally preheated by contact with the product material in a cooler. Table 1 summarises these processes and the furnace technologies they use. These industries are described in more detail in linked Combustion Files (see bottom of this text for the links).
Industry |
Process |
Process Temp |
Furnace type |
Linked CF |
Lime |
CaCO3 to CaO |
850 – 950oC |
shaft kiln, rotary kiln, fluid bed |
259 |
Pulp & Paper |
CaCO3 to CaO |
850 – 950oC |
rotary kiln, fluid bed |
259 |
Dolomite |
CaCO3.MgCO3 to CaO.MgO |
>1050oC |
shaft kiln, rotary kiln |
259 |
Cement |
CaCO3 to CaO followed by combination with Al2O3,SiO2 & Fe2O3 |
1450oC |
rotary kiln, shaft kiln |
260 |
Alumina |
Al2O3.3H2O to Al2O3 |
1100oC |
flash furnace, fluid bed, rotary kiln |
261 |
Dead-burnt Magnesite |
MgCO3 to MgO |
~1650oC |
shaft kiln, rotary kiln |
262 |
Dead-burnt Petroleum Coke |
Removal of volatiles from Green Coke to make ‘pure carbon’ |
~1100oC |
rotary kiln, fluid bed |
263 |
Chromium |
Extraction from chromite ore with soda ash to yield soluble sodium chromate Na2CrO4 |
1200oC |
rotary kiln |
264 |
Titanium Dioxide & Synthetic Rutile |
TiO(OH)2 to TiO2 or coal redox of ilmenite to rutile |
950oC 1200oC |
rotary kiln (sulphate route), chloride route |
265 |
De-fluorinated Phosphate |
Thermal degradation of Apatite to sodium phosphate |
~1300oC |
rotary kiln |
|
Aluminium Oxalate & Liquor Burning |
Incineration of organo-sodium aluminates |
~1100oC |
rotary kiln |
|
Table 1 Major industries in the minerals processing sector
Sources
Author