• What are the minerals processing industries ?

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    • Post Author

      espadmin

1. Introduction

The minerals processing industries constitute the largest annual tonnage manufacturers on a worldwide basis, of which some 1500millon tonnes per annum of minerals are processed at temperatures in excess of 1000oC. The general term for high temperature (<800oC) processing of material is [GLOSS]calcination[/GLOSS], and the term bears no relationship to the particular chemical or physical changes that are effected in the kiln. Over 80% of this production is dedicated to the manufacture of cements which consumes >5000PJ.p.a. of primary energy, mainly in the form of [GLOSS]coal[/GLOSS].

2. Minerals processing

Typical industries that fall within the minerals processing sector include:

·          Cement

·          Lime

·          Alumina

·          Magnesite

·          Chromium and titanium dioxide

Other related operations, such as:

·          dead burnt petroleum coke production and

·          metal ore fines roasting

may also be considered within this sector as they use similar technologies. 

Whilst the individual process thermodynamics and chemistry requirements are different for the type of minerals being processed there are some basic similarities in the process cycles and equipment used. Counter-current flow of process material and process gases tends to be a common design feature, whereby the feed of raw material is preheated/pre-processed by the flue gases from the primary furnace(s). The primary furnace(s) calcine the product, heat being supplied by direct contact with a diffusion flame. The combustion air to the furnace is generally preheated by contact with the product material in a cooler. Table 1 summarises these processes and the furnace technologies they use.  These industries are described in more detail in linked Combustion Files (see bottom of this text for the links).

 

Industry

Process

Process Temp

Furnace type

Linked CF

Lime

CaCO3  to  CaO

850 – 950oC

shaft kiln, rotary kiln, fluid bed

259

Pulp & Paper

CaCO3  to  CaO 

850 – 950oC

rotary kiln, fluid bed

259

Dolomite

CaCO3.MgCO3 to  CaO.MgO

>1050oC

shaft kiln, rotary kiln

259

Cement

CaCO3  to  CaO followed by combination with Al2O3,SiO2 & Fe2O3

1450oC

rotary kiln, shaft kiln

260

Alumina

Al2O3.3H2O  to Al2O3

1100oC

flash furnace, fluid bed, rotary kiln

261

Dead-burnt Magnesite

MgCO3  to  MgO

~1650oC

shaft kiln, rotary kiln

262

Dead-burnt Petroleum Coke

Removal of volatiles from Green Coke to make ‘pure carbon’

~1100oC

rotary kiln, fluid bed

263

Chromium

Extraction from chromite ore with soda ash to yield soluble sodium chromate Na2CrO4

1200oC

rotary kiln

264

Titanium Dioxide & Synthetic Rutile

TiO(OH)2  to TiO2 or coal redox of ilmenite to rutile

950oC

1200oC

rotary kiln (sulphate route), chloride route

265

De-fluorinated Phosphate

Thermal degradation of Apatite to sodium phosphate

~1300oC

rotary kiln

 

Aluminium Oxalate & Liquor Burning

Incineration of organo-sodium aluminates

~1100oC

rotary kiln

 

Table 1 Major industries in the minerals processing sector

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